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FIGURE 32.1 Specific volume versus temperature. (A) Glass with a transition temperature Tg ; (B) a crystal that melts at a fixed temperature Tm , such as a pure element or a compound; (C) a crystal that melts over a range of temperature, such as a solid-solution alloy with TL the liquidus temperature and Ts the solidus temperature.

Distributed queries The user should be able to join data from any of the tables in the (distributed) database, even if the tables are located on different physical systems Distributed updates The user should be able to update data in any table for which the user has the necessary privileges, whether that table is on the local system or on a remote system Distributed transactions The DBMS should support distributed transactions (using COMMIT and ROLLBACK) across system boundaries, maintaining the integrity of the (distributed) database even in the face of network failures and failures of individual systems Security The DBMS must provide a security scheme adequate to protect the entire (distributed) database from unauthorized forms of access Universal access The DBMS should provide universal, uniform access to all of the organization s data.

When hot liquid glass is cooled to some temperature Tg , called the glass transition temperature, there is an abrupt change in the slope of the specific volume versus temperature curve. Unlike crystalline solids, the glass shows no marked decrease in specific volume at this temperature. Below Tg , glass behaves as a typical solid.

No current distributed DBMS product even comes close to meeting this ideal, and it s unlikely that any product ever will In practice, formidable obstacles make it difficult to provide even simple forms of distributed database management These obstacles include Performance In a centralized database, the path from the DBMS to the data has an access speed of a few milliseconds and a data transfer rate of millions of characters per second Even on a fast local area network, access speeds lengthen to hundredths or tenths of a second, and transfer rates can fall to 100,000 characters per second or less On a modem link, data access may take seconds or minutes, and a few thousand characters per second may be the maximum effective throughput This vast difference in speeds can dramatically slow the performance of remote data access.

Performance Streaming media benefits from excellent coding efficiency and robustness in error-prone environments such as the Internet. Interoperability A cross-platform open standard that can run on a multitude of devices and work well at all supported bit rates, over a variety of delivery networks and technologies. Scalability Video quality can be adjusted in response to network congestion in a media format that is encoded once and played anywhere. Interactivity Since a scene is composed of individual media objects, users can manipulate each one individually. Animated objects can be mixed with natural objects. The user can discard media objects at the player, making it possible to view any objects desired.

32.3.2 Molecular Solids A molecule is a group of atoms that are held together by strong ionic or covalent bonds. A molecular solid is a structure made up of molecules that are attracted to each other by weak van der Waals forces. The two most common types of molecular solids are silicates and polymers. The silicates have ionic intramolecular bonds, and the polymers have covalent ones. Since it is the latter materials that are more important in terms of mechanical properties, they will be discussed in more detail. Polymers are organic compounds of carbon, hydrogen, and oxygen to which other elements such as chlorine or fluorine may be added. They cover a wide range of structural arrangements, with resulting variations in properties. Large molecules are constructed from a repeating pattern of small structural units. The hydrocarbons have repeating structural units of carbon and hydrogen atoms. Figure 32.2 shows some of the more common monomers or unsaturated molecules that are used in the building of macromolecules. The simplest monomer is ethylene (C2H4); it is shown in Fig. 32.2a. It is the base of the group of hydrocarbons called olefins. The olefins have the chemical formula CnH2n. The benzene molecule, shown in Fig. 32.2d, is another important building unit. Because of the shape of the molecule, it is described as a ring molecule or compound. The benzene group is also called the aromatic hydrocarbons. Figure 32.3 illustrates the addition polymerization of the ethylene monomer. The double bonds of ethylene are broken in the presence of a catalyst such as boron tri-